Fossil fuels are natural energy sources formed over millions of years from the remains of ancient organisms.
The three main fossil fuels are:
Coal – A solid fuel mainly composed of carbon.
Natural Gas – A gaseous fuel primarily composed of the hydrocarbon methane (CH₄).
Petroleum (Crude Oil) – A complex liquid mixture of hydrocarbons that can be separated into useful fractions through fractional distillation.
Hydrocarbons are compounds made up of only carbon and hydrogen atoms.
Examples:
Methane (CH₄) – The simplest hydrocarbon.
Ethane (C₂H₆) and Propane (C₃H₈) – Also found in natural gas.
Octane (C₈H₁₈) – A component of petrol.
Fractional distillation is a process that separates crude oil into useful fractions based on boiling points.
Process:
Crude oil is heated to 450°C and enters a fractionating column.
The column has a temperature gradient (hot at the bottom, cool at the top).
Different hydrocarbon fractions condense at different heights based on their boiling points.
Small molecules (lower boiling points) rise higher, while large molecules (higher boiling points) stay lower.
Each fraction is collected and used for different purposes.
From bottom (large molecules) to top (small molecules), fractions change as follows:
Bottom of Column (e.g., Bitumen) - to - Top of Column (e.g., Refinery Gas)
Chain Length - Longer hydrocarbon chains - to - Shorter hydrocarbon chains
Volatility - Low (does not evaporate easily) - to - High (evaporates easily)
Boiling Point - High (above 350°C) - to - Low (below 25°C)
Viscosity - Thick & Sticky - to - Thin & Runny
Each fraction has different uses based on chain length and boiling point.
Refinery Gas - Used as gas for heating and cooking (contains methane, ethane, propane, butane).
Gasoline (Petrol) - Used as fuel for cars.
Naphtha - Used as a chemical feedstock to make plastics, medicines, and dyes.
Kerosene (Paraffin) - Used as jet fuel and heating oil.
Diesel Oil (Gas Oil) - Used as fuel for diesel engines (trucks, trains).
Fuel Oil - Used as fuel for ships and home heating.
Lubricating Oil - Used in lubricants, waxes, and polishes.
Bitumen - Used for road surfacing and roofing.
The molecular formula of a compound tells us:
The exact number of atoms of each element present in a single molecule.
The type of atoms in the molecule (i.e., which elements it contains).
Examples of Molecular Formulae:
Water = H₂O (2 hydrogen atoms, 1 oxygen atom)
Methane = CH₄ (1 carbon atom, 4 hydrogen atoms)
Ethanol = C₂H₆O (2 carbon, 6 hydrogen, 1 oxygen atom)
Glucose = C₆H₁₂O₆ (6 carbon, 12 hydrogen, 6 oxygen atoms)
The empirical formula of a compound represents the simplest whole-number ratio of atoms or ions present in the compound. Unlike the molecular formula, it does not show the exact number of atoms—only their simplest ratio.
Examples of Empirical Formulae:
Hydrogen Peroxide (H₂O₂) = HO (The ratio of hydrogen to oxygen is simplified from 2:2 to 1:1)
Glucose (C₆H₁₂O₆) = CH₂O (The ratio 6:12:6 simplifies to 1:2:1)
Ethene (C₂H₄) = CH₂ (The ratio 2:4 simplifies to 1:2)
Water (H₂O) = H₂O (Already in its simplest form so cannot be simplified)
The displayed formula of a molecule shows all the atoms and all the bonds between them.
Examples:
Ethene (C₂H₄)
H H
| |
C ═ C
| |
H H
Ethanol (C₂H₅OH)
H H
l l
H - C - C - O - H
l l
H H
A structural formula is a clear way to show how atoms are arranged in a molecule without drawing every bond explicitly.
Examples:
Ethene: CH₂=CH₂
Ethanol: CH₃CH₂OH
Methyl ethanoate (an ester): CH₃COOCH₃
Structural isomers are compounds with the same molecular formula but different structural arrangements of atoms.
Examples of Structural Isomers:
Butane (C₄H₁₀) Isomers:
Straight-chain butane: CH₃CH₂CH₂CH₃
Branched isomer (2-methylpropane): CH₃CH(CH₃)CH₃
Butene (C₄H₈) Isomers:
But-1-ene: CH₃CH₂CH=CH₂
But-2-ene: CH₃CH=CHCH₃
These isomers have different physical and chemical properties due to variations in structure.
A functional group is a specific atom or group of atoms that determines the chemical properties of a homologous series.
A homologous series is a family of organic compounds that:
Have a similar chemical structure.
Contain the same functional group, which determines their chemical properties.
Follow the same general formula.
Examples of Homologous Series:
Alkanes:
Alkanes are saturated hydrocarbons (contain only single bonds). They are less reactive than unsaturated compounds.
General formula: CₙH₂ₙ₊₂
Functional group: None (only single bonds)
Examples: Methane (CH₄), Ethane (C₂H₆)
Alkenes:
Alkenes are unsaturated hydrocarbons (contain at least one double bond). They are more reactive than unsaturated compounds.
General formula: CₙH₂ₙ
Functional group: C=C (double bond)
Examples: Ethene (C₂H₄), Propene (C₃H₆)
Alcohols:
General formula: CₙH₂ₙ₊₁OH
Functional group: –OH (hydroxyl group)
Examples: Methanol (CH₃OH), Ethanol (C₂H₅OH)
Carboxylic acids:
General formula: CₙH₂ₙ₊₁COOH
Functional group: –COOH (carboxyl group)
Examples: Methanoic Acid (HCOOH), Ethanoic Acid (CH₃COOH)
Differ by a –CH₂– Unit
Each successive compound differs by a CH₂ (methylene) group.
Example: Methanol (CH₃OH) → Ethanol (C₂H₅OH) → Propanol (C₃H₇OH).
Gradual Trend in Physical Properties
As the number of carbon atoms increases, properties like boiling point, melting point, and viscosity change in a predictable way.
Example: Boiling points of alkanes increase as chain length increases due to stronger intermolecular forces.
Similar Chemical Properties
Since they have the same functional group, they undergo similar reactions.
Example: All alkenes react with bromine water in an addition reaction to turn it colorless.
Alkanes are saturated hydrocarbons. They are less reactive than unsaturated compounds.
General formula: CₙH₂ₙ₊₂
Functional group: None, alkanes have single covalent bonds between carbon atoms (C–C).
Have the suffix -ane.
Methane: The simplest alkane with single C–H bonds.
Molecular formula: CH₄
Empirical formula: CH₄
Structural Formula: CH₄
Displayed formula:
H
|
H—C—H
|
H
Ethane
Molecular formula: C₂H₆
Empirical formula: CH₃
Structural formula: CH₃CH₃
Displayed formula:
H H
| |
H—C—C—H
| |
H H
Propane
Molecula formula: C₃H₈
Empirical formula: C₃H₈
Structural Formula: CH₃CH₂CH₃
Displayed formula:
H H H
| | |
H—C—C—C—H
| | |
H H H
Butane
Molecular formula: C₄H₁₀
Empirical formula: C₂H₅
Structural Formula: CH₃CH₂CH₂CH₃
Displayed formula:
H H H H
| | | |
H—C—C—C—C—H
| | | |
H H H H
Generally Unreactive: Alkanes do not react easily because their C–C and C–H bonds are strong and nonpolar.
Combustion: Alkanes burn in oxygen to form carbon dioxide (CO₂) and water (H₂O).
Complete combustion: CH₄ + 2O₂ → CO₂ + 2H₂O
Incomplete combustion (limited oxygen) produces carbon monoxide (CO) or carbon (soot).
Substitution Reactions with Chlorine: Alkanes react with chlorine under UV light.
A substitution reaction occurs when one atom or group of atoms is replaced by another atom or group.
In alkanes, substitution reactions happen with halogens (e.g., chlorine).
Activation energy (Eₐ) is provided by UV light, breaking Cl₂ into chlorine radicals (Cl•).
Example: Methane and Chlorine Reaction
Equation:
Methane + chlorine → chloromethane + hydrochloric acid
CH₄ + Cl₂ → CH₃Cl + HCl
H
|
H—C—Cl
|
H
If the reaction continues, further substitution can occur, forming dichloromethane (CH₂Cl₂), trichloromethane (CHCl₃), or even tetrachloromethane (CCl₄).
Alkenes are unsaturated hydrocarbons (contain at least one double bond). They are more reactive than unsaturated compounds.
General formula: CₙH₂ₙ
Functional group: Alkenes contain at least one C=C double bond.
Have the suffix -ene.
Ethene
Molecular formula: C₂H₄
Empirical formula: CH₂
Structural Formula: CH₂=CH₂
Displayed formula:
H H
| |
C═C
| |
H H
Propene
Molecular formula: C₂H₄
Empirical formula: CH₂
Structural Formula: CH₂=CH₂
Displayed formula:
H H H
| | |
H—C—C═C—H
|
H
But-1-ene
Molecular formula: C₄H₈
Empirical formula: CH₂
Structural Formula: CH₃CH₂CH=CH₂
Displayed formula:
H H H H
| | | |
H—C—C—C═C—H
| |
H H
But-2-ene
Molecular formula: C₄H₈
Empirical formula: CH₂
Structural Formula: CH₃CH=CHCH₃
Displayed formula:
H H H H
| | | |
H—C—C═C—C—H
| |
H H
Cracking is the process of breaking down large alkane molecules from crude oil into smaller, alkenes and hydrogen.
Reasons for cracking:
To produce smaller, more useful hydrocarbons (e.g., gasoline, diesel).
To make more valuable alkenes, which are used to manufacture plastics and chemicals.
To produce hydrogen gas (H₂), which is used in fuel and ammonia production.
This process requires:
High temperature (~600-700°C)
A catalyst (e.g., alumina or silica)
Example Reaction:
C10H22 → C5H10 + C3H6 + H2
Bromine water (aqueous bromine) test distinguishes between alkanes (saturated) and alkenes (unsaturated).
Alkane (saturated) = No reaction = Bromine water stays orange
Alkene (unsaturated) = Addition reaction occurs = Bromine water turns colorless
In an addition reaction, a molecule adds across the C=C double bond.
Unlike substitution reactions (which produce multiple products), only one product is formed.
Examples:
Bromine (Br₂) – Test for Unsaturation
Reaction with bromine in atmospheric conditions:
ethene + bromine → Dibromoethane
C₂H₄ + Br₂ → C₂H₄Br₂
Structural formula for dibromoethane: CH₂BrCH₂Br
Displayed formula for dibromoethane:
Br H
| |
H—C—C—H
| |
H Br
Hydrogen (H₂) – Hydrogenation
Reaction with hydrogen in the presence of a nickel catalyst (150°C):
Ethene + hydrogen → Ethane
C₂H₄ + H₂ → C₂H6
Steam (H₂O) – Hydration
Reaction with steam in the presence of an acid catalyst (e.g., phosphoric acid, H₃PO₄):
Ethene + water → Ethanol
C₂H₄ + H₂O → C₂H5OH
General formula: CₙH₂ₙ₊₁OH
Functional group: –OH (hydroxyl group)
Have the suffix -ol.
Methanol
Molecular formula: CH₃OH
Empirical formula: CH₃OH
Structural Formula: CH₄
Displayed formula:
H
|
H—C—O—H
|
H
Ethanol
Molecular formula: C₂H₅OH
Empirical formula: C₃H₇OH
Structural formula: CH₃CH₂CH₂CH₃
Displayed formula:
H H
| |
H—C—C—O—H
| |
H H
Propan-1-ol
Molecular formula: C₃H₇OH
Empirical formula: C₃H₇OH
Structural Formula: CH₃CH₂CH₂OH
Displayed formula:
H H H
| | |
H—C—C—C—O—H
| | |
H H H
Propan-2-ol
Molecular formula: C₃H₇OH
Empirical formula: C₃H₇OH
Structural Formula: CH₃CH(OH)CH₃
Displayed formula:
H H H
| | |
H—C—C—C—H
| | |
H O H
|
H
Butan-1-ol
Molecular formula: C₄H₉OH
Empirical formula: C₄H₉OH
Structural Formula: CH₃CH₂CH₂CH₂OH
Displayed formula:
H H H H
| | | |
H—C—C—C— C—O—H
| | | |
H H H H
Butan-2-ol
Molecular formula: C₄H₉OH
Empirical formula: C₄H₉OH
Structural Formula: CH₃CH(OH)CH₂CH₃
Displayed formula:
H H H H
| | | |
H—C—C—C—C—H
| | | |
H H O H
|
H
Raw Material: Glucose (from plants, e.g., sugarcane, corn).
Conditions Required:
Temperature: 25–35°C (optimal for yeast enzyme activity).
Yeast (contains enzymes to convert glucose into ethanol).
Absence of oxygen (anaerobic conditions to prevent oxidation to carbon dioxide and water).
Reaction:
Glucose → ethanol + carbon dioxide
C6H1₂O6 → C₂H₅OH + 2CO₂
Process:
Glucose is broken down by yeast into ethanol and carbon dioxide.
The process stops when ethanol reaches ~15% concentration because alcohol kills yeast.
Ethanol is then purified by fractional distillation.
Advantages
Uses renewable resources (e.g., plants).
Requires low energy input.
Can be produced in developing countries.
Disadvantages
Slow process (batch process).
Produces impure ethanol (requires distillation).
Requires large areas of farmland, which may lead to food shortages.
Raw Material: Ethene (from crude oil cracking).
Conditions Required:
Temperature: 300°C
Pressure: 6000 kPa (60 atm)
Catalyst: Phosphoric acid (H₃PO₄) catalyst
Reaction:
Ethene + water → ethanol
C₂H4 + H₂O → C₂H₅OH
Process:
Ethene reacts with steam in the presence of an acid catalyst to form ethanol.
The product is then condensed and purified.
Advantages
Fast, continuous process.
Produces pure ethanol (no need for distillation).
More efficient and scalable.
Disadvantages
Uses non-renewable resources (crude oil).
Requires high temperature and pressure, increasing costs.
Not sustainable in the long term.
(a) As a Solvent
Dissolves substances that water cannot (e.g., paints, perfumes, medicines, and cosmetics).
Used in industrial processes and chemical extractions.
(b) As a Fuel
Used as bioethanol (a renewable fuel).
Mixed with petrol to reduce carbon emissions (e.g., E10 fuel: 10% ethanol, 90% petrol).
Used in spirit burners and alcohol stoves.
Ethanol is a renewable fuel that burns efficiently in oxygen.
Complete combustion reaction:
Ethanol + oxygen → carbon dioxide + water
C₂H₅OH + 3O₂ → 2CO₂ + 3H₂O
Observation: Ethanol burns with a clean blue flame.
General formula: CₙH₂ₙ₊₁COOH
Functional group: –COOH (carboxyl group)
Have the suffix -oic acid.
Methanoic acid
Molecular formula: CH₂O₂
Empirical formula: CH₂O₂
Structural Formula: HCOOH
Displayed formula:
O
||
H—C—O—H
Ethanoic acid
Molecular formula: C₂H₄O₂
Empirical formula: CH₃OH
Structural Formula: CH₃COOH
Displayed formula:
H O
| ||
H—C—C—O—H
|
H
Propanoic acid
Molecular formula: C3H6O₂
Empirical formula: CH₃OH
Structural Formula: CH3CH2COOH
Displayed formula:
H H O
| | ||
H—C—C—C—O—H
| |
H H
Butanoic acid
Molecular formula: C₄H8O₂
Empirical formula: CH₃OH
Structural Formula: CH3CH2CH2COOH
Displayed formula:
H H H O
| | | ||
H—C—C—C—C—O—H
| | |
H H H
Reaction with Metals
When ethanoic acid reacts with a reactive metal (e.g., magnesium or zinc), hydrogen gas is released, and a metal ethanoate (salt) is formed.
General Equation:
Metal + Ethanoic Acid → Metal Ethanoate + Hydrogen
Example: Reaction with Magnesium
Magnesium + Ethanoic Acid → Magnesium Ethanoate + Hydrogen
Mg + 2CH3COOH → (CH3COO)₂Mg + H₂
Reaction with Bases (Neutralisation Reaction)
Ethanoic acid reacts with metal hydroxides or oxides (bases) to form a salt (metal ethanoate) and water.
General Equation:
Ethanoic Acid + Base → Salt + Water
Example: Reaction with Sodium Hydroxide
Ethanoic Acid + Sodium hydroxide → Sodium ethanoate + Water
CH3COOH + NaOH → CH3COONa + H₂O
Reaction with Carbonates
Ethanoic acid reacts with metal carbonates to produce carbon dioxide, water, and a salt.
General Equation:
Ethanoic Acid + Metal Carbonate → Salt + carbon dioxide + water
Example: Reaction with Sodium Carbonate
Ethanoic acid + sodium carbonate → sodium ethanoate + carbon dioxide + water
2CH3COOH + Na₂CO3 → 2CH3COONa + CO₂ + H₂O
Oxidation using Acidified Potassium Manganate(VII) (KMnO₄)
Ethanol can be oxidized to ethanoic acid using acidified potassium manganate(VII).
The purple KMnO₄ solution turns colorless as it oxidizes ethanol.
Equation:
C₂H₅OH + [O] → CH3COOH + H₂O
Oxidation by Bacterial Action (Vinegar Production)
Ethanol in wine or cider is oxidized by bacteria (acetobacter) in the presence of oxygen to form ethanoic acid.
This process happens in the production of vinegar.
Equation:
C₂H₅OH + O₂ → CH3COOH + H₂O
Ethanoic acid reacts with alcohols in the presence of a strong acid catalyst (e.g., concentrated sulfuric acid) to form esters and water.
General Equation:
Carboxylic Acid + Alcohol → Ester + Water
Example: Formation of Ethyl Ethanoate
Ethanoic acid + Ethanol → Ethyl ethanoate + Water
CH₃COOH + C₂H5OH → CH₃COOC₂H₃ + H₂O
Displayed Formula for Ethyl Ethanoate:
H O H H
| || | |
H—C—C—O—C—C—H
| | |
H H H
Observation: A sweet-smelling ester is formed.
Application: Used in perfumes, flavorings, and solvents.
Polymers are large molecules formed by linking many small molecules called monomers.
The process of forming polymers is known as polymerisation.
Examples of Polymers:
Natural Polymers: Cellulose, proteins, DNA.
Synthetic Polymers: Poly(ethene), nylon, polyester.
Addition polymerisation is a process where monomers with double bonds (like ethene) join together to form a polymer without losing any small molecules.
Formation of Poly(ethene):
Monomer: Ethene (CH₂=CH₂)
Polymer: Poly(ethene) or polyethylene
Reaction: Double bonds in ethene monomers open up and link together to form a long chain.
Equation:
n CH₂=CH₂ → −(CH₂−CH₂)−n
Displayed Formula:
H H H H H H H H
| | | | | | | |
C = C + C = C → — C—C—C—C—
| | | | | | | |
H H H H H H H H
Poly(ethene) is flexible, durable, and waterproof, making it ideal for plastic bags, bottles, and containers.
Monomers: Alkenes
Reaction Type: Opening of a C=C bond
By-products: No by-product
Example Polymer: Poly(ethene), Poly(propene)
Formation of Poly(ethene)
Monomer: Ethene (CH₂=CH₂)
Polymer: Poly(ethene)
Reaction:
Monomers: Monomers with two functional groups
Reaction Type: Reaction between two different monomers
By-products: Small molecule (H₂O or HCl) is released
Example Polymer: Nylon (polyamide), PET (polyester)
(a) Formation of polyamides (e.g., Nylon)
Monomers:
Dicarboxylic acid (HOOC–R–COOH)
Diamine (H₂N–R–NH₂)
Reaction:
Dicarboxylic acid + Diamine → Polyamide + Water
Monomers of nylon:
Nylon polymer:
(b) Formation of polyesters (e.g., PET)
Monomers:
Dicarboxylic acid (HOOC–R–COOH)
Diol (HO–R–OH)
Reaction:
Dicarboxylic acid + Diol → Polyester + Water
Monomers of PET:
PET polymer:
PET can also be broken down into its original monomers and re-polymerized to form new plastic products.
Proteins are polymers made from amino acid monomers.
The amide bonds in proteins are called peptide bonds.
Amino Acid General Structure:
Proteins have similar bonding to nylon, making them natural polyamides.
Plastics are synthetic materials made from polymers.
They are lightweight, durable, and moldable, which makes them suitable for various applications like packaging, electronics, and textiles.
The properties that make plastics useful also create disposal challenges:
Durability: Plastics take hundreds of years to decompose, leading to long-term environmental impacts.
Resistance to Chemicals: Limits the breakdown of plastics in natural environments.
Lightweight: Easily transported by wind and water, contributing to widespread pollution.
(a) Disposal in Landfill Sites
Plastics occupy large volumes in landfills.
Slow decomposition leads to long-lasting environmental clutter.
Potential release of toxic chemicals into soil and groundwater.
(b) Accumulation in Oceans
Plastics enter oceans through rivers, drains, and littering.
Marine life ingestion of plastics leads to injury or death.
Formation of microplastics (tiny plastic particles) that enter food chains.
(c) Formation of Toxic Gases from Burning
Incinerating plastics can release harmful gases like dioxins and furans, which are toxic and carcinogenic.
Contributes to air pollution and climate change.
Addition Reaction: A chemical reaction where a molecule adds across a double bond, forming a single product.
Alcohols: A homologous series of organic compounds containing a hydroxyl (-OH) functional group.
Alkanes: A homologous series of saturated hydrocarbons, which have only single bonds between carbon atoms.
Alkenes: A homologous series of unsaturated hydrocarbons, containing at least one carbon-carbon double bond.
Carboxylic Acids: A homologous series of organic compounds containing a carboxyl (-COOH) functional group.
Catalyst: A substance that speeds up a chemical reaction without being consumed in the reaction.
Condensation Polymerisation: A type of polymerisation where monomers join together and a small molecule, such as water, is released as a by-product.
Displayed Formula: A diagram showing all atoms and all bonds between them in a molecule.
Empirical Formula: The simplest whole-number ratio of atoms in a compound.
Esters: Organic compounds formed from the reaction between an alcohol and a carboxylic acid.
Fermentation: An anaerobic biochemical process where a substance is broken down by enzymes (typically from yeast), producing alcohol.
Fractional Distillation: A process used to separate crude oil into different fractions based on boiling point.
Functional Group: A specific atom or group of atoms within a molecule that is responsible for the molecule’s characteristic chemical reactions.
Homologous Series: A family of organic compounds with similar structures, the same functional group, and that follow a general formula.
Hydrocarbons: Organic compounds made up only of carbon and hydrogen atoms.
Hydration: A chemical reaction that involves the addition of water to a molecule.
Molecular Formula: A chemical formula that shows the exact number and type of atoms in a molecule.
Monomers: Small molecules that combine to form polymers.
Polymerisation: The process of joining small molecules (monomers) together to form a large molecule (polymer).
Polymers: Large molecules made up of many repeating smaller units (monomers).
Saturated Hydrocarbon: A hydrocarbon that contains only single bonds between carbon atoms.
Structural Formula: A formula that represents how atoms are arranged in a molecule without showing every bond explicitly.
Structural Isomers: Compounds with the same molecular formula but different structural arrangements of atoms.
Substitution Reaction: A reaction in which one atom or group of atoms is replaced by another atom or group.
Unsaturated Hydrocarbon: A hydrocarbon containing at least one double or triple bond between carbon atoms.